10 research outputs found

    State estimation-based centralized substation protection scheme

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    Power systems are experiencing drastic changes with the introduction of renewable and customer-owned resources. These changes introduce new challenges in the protection, control, and operation of power systems. They are concurrent with utilities’ efforts to boost system reliability. Such efforts are undermined by the vulnerability of protection system to hidden failures. Accordingly, it is necessary to develop new methods that can cope with new characteristics and avoid relay misoperations because of hidden failures. This dissertation introduces a new dynamic state estimation-based centralized protection scheme (DSEBCPS) at the substation level. This system supplements dynamic state estimation-based protection for individual zones known as “settingless relays” to secure their operation against hidden failures. The DSEBCPS communicates with the settingless relays via the station bus and obtains essential information from each protection zone, such as phasor quantities and status of breakers and disconnects. This information is processed by the DSEBCPS to extract the substation topology and states. Specifically, the DSEBCPS performs dynamic state estimations in the quasi-dynamic domain once per cycle to detect any sort of abnormality within the substation. Upon detecting abnormalities, the DSEBCPS performs hypothesis testing to distinguish between faults and hidden failures. The DSEBCPS detects and locates hidden failures within the substation through hypothesis testing. Then, the DSEBCPS streams the estimated measurements that corresponds to the detected bad measurements to the settingless relay to override the compromised measurement. Its capability to detect hidden failures and replace the compromised measurements in real time secure settingless relays from misoperation and ensure high dependability even with the presence of hidden failures. Such capability bridges a critical gap in protection systems. Critical to this work is the ability to manage data and communications between the various devices (i.e., MUs, settingless relays, and DSEBCPS) within the substation and between the substation and the control center. Therefore, this thesis includes the proposed system architecture, which specifies data management, communication protocols, and the hierarchical structure of the system.Ph.D

    Cyclohexylammonium Hexaisothiocyanatonickelate(II) Dihydrate as a Single-Source Precursor for High Surface Area Nickel Oxide and Sulfide Nanocrystals

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    Cyclohexylammonium hexaisothiocyanatonickelate(II) dihydrate, (C6H11NH3)4[Ni(NCS)6]·2H2O, was synthesized, for the first time, by a four-step method in a yield of 95%. The compound was fully characterized by elemental microanalysis, Fourier transform infrared (FTIR), ultraviolet-visible-near infrared (UV-Vis-NIR), and nuclear magnetic resonance (NMR) spectroscopy and thermogravimetry. A single crystal X-ray diffraction (SXRD) gave the monoclinic space group P21/c with a = 15.8179 (5) Å, b = 10.6222 (3) Å, c = 13.8751 (4) Å, β = 109.362 (1)°, V = 2199.45 (11) Å3, Z = 2 (T = 293 K) for this novel hybrid organic–inorganic compound. The title compound was employed as a single-source precursor for the synthesis of mesoporous, high surface area nickel oxide (53 Å; 452 m2/g) and nickel sulfide (46 Å; 220 m2/g) via pyrolysis under air at 550 °C or helium atmosphere at 500 °C, respectively. X-ray powder diffraction (XRPD) demonstrated the nanocrystalline nature of both NiO and NiS with an average crystallite size of 16 and 54 nm, respectively. Scanning electron microscope (SEM) indicated the formation of agglomerated, quasi-spherical particles of nickel oxide and agglomerated flake-like structures of nickel sulfide. The high surface area, porosity, and nanocrystallinity of both NiO and NiS, obtained via this approach, are promising for a wide spectrum of applications

    Cyclohexylammonium Hexaisothiocyanatonickelate(II) Dihydrate as a Single-Source Precursor for High Surface Area Nickel Oxide and Sulfide Nanocrystals

    No full text
    Cyclohexylammonium hexaisothiocyanatonickelate(II) dihydrate, (C6H11NH3)4[Ni(NCS)6]·2H2O, was synthesized, for the first time, by a four-step method in a yield of 95%. The compound was fully characterized by elemental microanalysis, Fourier transform infrared (FTIR), ultraviolet-visible-near infrared (UV-Vis-NIR), and nuclear magnetic resonance (NMR) spectroscopy and thermogravimetry. A single crystal X-ray diffraction (SXRD) gave the monoclinic space group P21/c with a = 15.8179 (5) Å, b = 10.6222 (3) Å, c = 13.8751 (4) Å, β = 109.362 (1)°, V = 2199.45 (11) Å3, Z = 2 (T = 293 K) for this novel hybrid organic–inorganic compound. The title compound was employed as a single-source precursor for the synthesis of mesoporous, high surface area nickel oxide (53 Å; 452 m2/g) and nickel sulfide (46 Å; 220 m2/g) via pyrolysis under air at 550 °C or helium atmosphere at 500 °C, respectively. X-ray powder diffraction (XRPD) demonstrated the nanocrystalline nature of both NiO and NiS with an average crystallite size of 16 and 54 nm, respectively. Scanning electron microscope (SEM) indicated the formation of agglomerated, quasi-spherical particles of nickel oxide and agglomerated flake-like structures of nickel sulfide. The high surface area, porosity, and nanocrystallinity of both NiO and NiS, obtained via this approach, are promising for a wide spectrum of applications

    Galaxies with a central minimum in stellar luminosity density

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    We used Hubble Space Telescope WFPC2 images to identify six early-type galaxies with surface brightness profiles that decrease inward over a limited range of radii near their centers. The inferred luminosity density profiles of these galaxies have local minima interior to their core break radii. NGC 3706 harbors a high surface brightness ring of starlight with radius ≈20 pc. Its central structure may be related to that in the double-nucleus galaxies M31 and NGC 4486B. NGC 4406 and NGC 6876 have nearly flat cores that, on close inspection, are centrally depressed. Colors for both galaxies imply that this is not due to dust absorption. The surface brightness distributions of both galaxies are consistent with stellar tori that are more diffuse than the sharply defined system in NGC 3706. The remaining three galaxies are the brightest cluster galaxies in A260, A347, and A3574. Color information is not available for these objects, but they strongly resemble NGC 4406 and NGC 6876 in their cores. The thin ring in NGC 3706 may have formed dissipatively. The five other galaxies resemble the endpoints of some simulations of the merging of two gas-free stellar systems, each harboring a massive nuclear black hole. In one version of this scenario, diffuse stellar tori are produced when stars initially bound to one black hole are tidally stripped away by the second black hole. Alternatively, some inward-decreasing surface brightness profiles may reflect the ejection of stars from a core during the hardening of the binary black hole created during the merger
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